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Last updateWed, 22 Nov 2017 2pm

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Unique Operating Dynamics of Trunnion-Mounted Ball Valves

Unique Operating Dynamics of Trunnion-Mounted Ball Valves

For a very long time, the idea has exist...

Adopting the IIoT: Are Results Matching the Hype?

Adopting the IIoT: Are Results Matching the Hype?

Many valve, actuator and control manufac...

Where Valves Are Used: Everywhere!

Where Valves Are Used: Everywhere!

Valves can be found just about anywhere ...

Oxygen Cleaning: A Validated Process is Critical for Safety

Oxygen Cleaning: A Validated Process is Critical for Safety

From time to time, we re-publish well-re...

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Industry Headlines

Conference Board Economic Index Rose in October

Tuesday, 21 November 2017  |  Chris Guy

The Conference Board Leading Economic Index (LEI) for the U.S. increased 1.2% in October to 130.4 (2010 = 100), following a 0.1% increase in September...

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Industry Headlines

VanAire Celebrates Manufacturing with ‘Industry After Hours’

3 DAYS AGO
VanAire Celebrates Manufacturing with ‘Industry After Hours’

On Nov. 8, Delta County, MI K-12 students and parents attended Industry After Hours at VanAire to learn more about the high tech, high skilled manufacturing jobs that are available. Over 276 participants were treated to a fun, entertaining and informative event that exceeded expectations and inspired ...

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Emerson Opens Solutions Center in Singapore

6 DAYS AGO

As part of its drive to make Singapore a hub for the delivery of Industrial Internet of Things (IoT) technologies and services for customers across Asia Pacific, Emerson opened a customer-focused Solutions Center at the regional headquarters of its Automation Solutions business in Singapore. To mark...

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Nebraska Approves Keystone XL Pipeline Route

3 DAYS AGO

By a vote of 3-2, the Nebraska Public Service Commission approved an order giving TransCanada the go ahead to build the Keystone XL Pipeline utilizing the proposed Mainline Alternative Route. This is one of three proposed routes included in the application filed by TransCanada Keystone Pipeline. L.P...

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Energy Outlook Shows a World in Transformation

9 DAYS AGO

The resurgence in oil and gas production from the United States, deep declines in the cost of renewables and growing electrification are changing the face of the global energy system and upending traditional ways of meeting energy demand, according to the World Energy Outlook 2017 . A cleaner and more...

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Conference Board Economic Index Rose in October

2 DAYS AGO

The Conference Board Leading Economic Index (LEI) for the U.S. increased 1.2% in October to 130.4 (2010 = 100), following a 0.1% increase in September, and a 0.4% increase in August.

“The U.S. LEI increased sharply in October, as the impact of the hurricanes dissipated,” said Ataman Ozyildi...

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U.S. Industrial Output Up 0.9% in October

6 DAYS AGO

Industrial production rose 0.9% in October, and manufacturing increased 1.3%. The index for utilities rose 2.0%, but mining output fell 1.3%, as Hurricane Nate caused a sharp but short-lived decline in oil and gas drilling and extraction. Even so, industrial activity was boosted in October by a return...

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NACE MR0103 and Duplex Stainless Steels

materials_q_and_a_graphicQ: Why are some suppliers reluctant to produce duplex stainless-steel valves that are compliant with NACE MR0103?

 

A: Duplex stainless steels are those that are chemically balanced to provide a target microstructure of 50% austenite phase and 50% ferrite phase. Duplex stainless-steel valves required to meet NACE MR0103 will almost always be installed in a sour, corrosive, chloride-containing environment, so it is essential the material provides optimized resistance to sulfide stress cracking, chloride stress corrosion cracking, chloride pitting and general corrosion.

 

The task group that created the NACE MR0103 document, “Materials Resistant to Sulfide Stress Cracking in Corrosive Petroleum Refining Environments,” recognized that microstructure is a key factor influencing the properties of duplex stainless steel. They also recognized that the microstructure is influenced strongly by chemistry and by heating and cooling during processing of the material. As a result, NACE MR0103 includes some very stringent requirements for duplex stainless steels, especially with regard to welding. Since most valve bodies (and many bonnets) are produced from castings, welding will be performed. Although most welding will be minor and cosmetic in nature, NACE MR0103 does not distinguish between minor and major weld repairs when it comes to welding requirements for these materials.

During welding, the cooling rates that occur in the weld deposit and in the heat-affected zone (HAZ) can have dramatic effects on the final microstructure. Higher cooling rates tend to promote higher ferrite levels, which are advantageous for chloride stress corrosion cracking resistance but detrimental to sulfide stress cracking resistance and impact resistance. Conversely, slower cooling rates promote lower ferrite levels, which will result in increased sulfide stress cracking resistance and toughness, but reduced chloride stress corrosion cracking resistance, and can allow the formation of harmful second phases that detract from the overall corrosion resistance of the material.

Therefore, successful welding of duplex stainless steels to provide optimum properties is a fine balancing act, which requires careful control of welding parameters that affect the cooling rate of the weldment.

Welding Requirements

In order to achieve the necessary control over cooling rates during welding, NACE MR0103 includes several requirements with regard to qualification of welding procedures:

  1. Each procedure qualification specimen must be hardness surveyed using to 10 kg Vickers hardness scale. The readings must average no more that 310 HV 10, and no individual reading is allowed to exceed 320 HV 10.
  2. The ferrite content must be measured metallographically in the weld deposit and HAZ of each procedure qualification specimen. The measured ferrite content must fall within the 35% to 65% range in all measured locations.
  3. The heat input required per the resulting welding procedure specification must not deviate by more than 10% from the heat input used when producing the procedure qualification specimen(s).
  4. The base metal thickness range qualified by a given procedure specimen of thickness T is 0.8T to 1.2T.

 

Requirements 1 and 2, although they add testing over and above the normal ASME Section IX requirements, are not overly problematic.

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