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Problem-Driven Innovation

Problem-Driven Innovation

Developing Alternative Technology to Imp...

Valve Repair Takes Center Stage in Houston

Valve Repair Takes Center Stage in Houston

Attendees gathered June 2-3 in Houston t...

What Internal Best Practices Can Do for Valve Selection

What Internal Best Practices Can Do for Valve Selection

As time goes by, technology moves forwar...

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Problem-Driven Innovation

Problem-Driven Innovation

Monday, 20 June 2016  |  Mark A. Lobo, P.E.

Developing Alternative Technology to Improve Product Performance

Industrial product engineering teaches us to understand the difference between problem...

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Industry Headlines

Curtiss-Wright Awarded Contracts for U.S. Naval Defense Platforms

2 DAYS AGO

Curtiss-Wright announced that it has been awarded contracts valued in excess of $80 million to provide valves for the U.S. Navy’s Virginia-class submarines and Ford-class aircraft carriers. The awards were received from Bechtel Plant Machinery, Inc. and General Dynamics Electric Boat Division ...

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DeZURIK Adds Dedicated Clean Room to Sartell Plant

4 DAYS AGO

In order to ensure proper cleaning procedures are performed on valves intended for oxygen, ozone, chlorine, hydrogen peroxide, isocyanate and other applications, DeZURIK has constructed a new dedicated clean room within its Sartell, MN manufacturing plant.

Operated by trained cleaning technicians, DeZU...

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Global Upstream Spending Slashed by $1 Trillion

2 DAYS AGO

Global upstream development spending from 2015 to 2020 has been cut by 22% or $740 billion since the oil price started to drop two years ago, according Wood Mackenzie's research . When you include cuts to conventional exploration investment, the figure increases to just over $1 trillion. Expect to see...

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EPA Bans Fracking Wastewater Disposal at Public Treatment Plants

4 DAYS AGO

The EPA has finalized a rule establishing pretreatment standards for discharges of wastewater from onshore unconventional oil and gas (UOG) extraction facilities to municipal sewage treatment plants (also known as publicly owned treatment works, or POTWs). The rule is designed to prevent the discharge...

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U..S. Durable Goods Orders Down 2.2% in May

1 DAY AGO

New orders for manufactured durable goods in May decreased $5.3 billion or 2.2% to $230.7 billion, the Commerce Department announced today. This decrease , down following two consecutive monthly increases, followed a 3.3% April increase. Excluding transportation, new orders decreased 0.3%. Excluding d...

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Federal Judge Halts New BLM Fracking Rules

2 DAYS AGO

“The Obama administration will fight a federal judge’s ruling overturning its effort to regulate hydraulic fracturing on public lands,” Bloomberg reports . The White House says they will take the case to the U.S. Court of Appeals.

“The ruling, issued late Tuesday by Wyoming-based...

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NACE MR0103 and Duplex Stainless Steels

materials_q_and_a_graphicQ: Why are some suppliers reluctant to produce duplex stainless-steel valves that are compliant with NACE MR0103?

 

A: Duplex stainless steels are those that are chemically balanced to provide a target microstructure of 50% austenite phase and 50% ferrite phase. Duplex stainless-steel valves required to meet NACE MR0103 will almost always be installed in a sour, corrosive, chloride-containing environment, so it is essential the material provides optimized resistance to sulfide stress cracking, chloride stress corrosion cracking, chloride pitting and general corrosion.

 

The task group that created the NACE MR0103 document, “Materials Resistant to Sulfide Stress Cracking in Corrosive Petroleum Refining Environments,” recognized that microstructure is a key factor influencing the properties of duplex stainless steel. They also recognized that the microstructure is influenced strongly by chemistry and by heating and cooling during processing of the material. As a result, NACE MR0103 includes some very stringent requirements for duplex stainless steels, especially with regard to welding. Since most valve bodies (and many bonnets) are produced from castings, welding will be performed. Although most welding will be minor and cosmetic in nature, NACE MR0103 does not distinguish between minor and major weld repairs when it comes to welding requirements for these materials.

During welding, the cooling rates that occur in the weld deposit and in the heat-affected zone (HAZ) can have dramatic effects on the final microstructure. Higher cooling rates tend to promote higher ferrite levels, which are advantageous for chloride stress corrosion cracking resistance but detrimental to sulfide stress cracking resistance and impact resistance. Conversely, slower cooling rates promote lower ferrite levels, which will result in increased sulfide stress cracking resistance and toughness, but reduced chloride stress corrosion cracking resistance, and can allow the formation of harmful second phases that detract from the overall corrosion resistance of the material.

Therefore, successful welding of duplex stainless steels to provide optimum properties is a fine balancing act, which requires careful control of welding parameters that affect the cooling rate of the weldment.

Welding Requirements

In order to achieve the necessary control over cooling rates during welding, NACE MR0103 includes several requirements with regard to qualification of welding procedures:

  1. Each procedure qualification specimen must be hardness surveyed using to 10 kg Vickers hardness scale. The readings must average no more that 310 HV 10, and no individual reading is allowed to exceed 320 HV 10.
  2. The ferrite content must be measured metallographically in the weld deposit and HAZ of each procedure qualification specimen. The measured ferrite content must fall within the 35% to 65% range in all measured locations.
  3. The heat input required per the resulting welding procedure specification must not deviate by more than 10% from the heat input used when producing the procedure qualification specimen(s).
  4. The base metal thickness range qualified by a given procedure specimen of thickness T is 0.8T to 1.2T.

 

Requirements 1 and 2, although they add testing over and above the normal ASME Section IX requirements, are not overly problematic.

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