08202017Sun
Last updateFri, 18 Aug 2017 1pm

i

Safety Relief Valve FAQs

Safety Relief Valve FAQs

Companies that repair, test, maintain or...

An Update on U.S. Valve-Related Standards

An Update on U.S. Valve-Related Standards

It takes much time and effort by many pe...

Diagnostics for Commissioning and Startup

Diagnostics for Commissioning and Startup

Many facilities have found value in perf...

Subscribe SUM17

FREE SUBSCRIPTION*

•  Print magazine
•  Digital magazine
•  VALVE eNews
Read the latest issue

*to qualified valve professionals in the U.S./Canada

The Weekly Report

New Products

  • ja-news-2
  • ja-news-3

Industry Headlines

Advertisement
i

Web Only

Safety Relief Valve FAQs

Safety Relief Valve FAQs

Monday, 14 August 2017  |  Lyndon Garrick

Companies that repair, test, maintain or supply valves routinely receive inquiries from end users about safety-relief valves. Here are a few questions...

Readmore

Loading...

Industry Headlines

Forum Energy Technologies Acquires Multilift

2 DAYS AGO

Forum Energy Technologies, Inc. has acquired the stock of Multilift from Pelican Energy Partners, a Houston-based oilfield services focused private equity fund, and management. Based in Houston, Multilift manufactures the patented SandGuard and the Cyclone completion tools; products that extend the ...

Readmore

ValvTechnologies Names Teele Director of Global Quality Management

4 DAYS AGO

ValvTechnologies, Inc. has appointed Michael Teele director of global quality management. Based in Houston, Teele will be responsible for setting and maintaining global quality standards, systems and processes, as well as serving as a leadership champion of continuous improvement. With a deep technic...

Readmore

Executive Order to Speed Up Infrastructure Project Approval

2 DAYS AGO

President Trump signed an executive order intended to roll back “rules regarding environmental reviews and restrictions on government-funded building projects in flood-prone areas as part of his proposal to spend $1 trillion to fix aging U.S. infrastructure,” Reuters reports .

“Trump's...

Readmore

DuPont and Dow Chemical Set Closing Date for Merger

3 DAYS AGO

DuPont and The Dow Chemical Company announced that all required regulatory approvals and clearances have been received, that all conditions to closing of their merger of equals have been satisfied, and that their merger of equals will close after the market closes on August 31, 2017.

“The compa...

Readmore

U.S. Factory Output Declined in July

1 DAY AGO

Manufacturing output edged down 0.1% in July. The index for durables decreased 0.5%. Among durable manufacturing industries, with the indexes for primary metals and for furniture and related products each dropped more than 1%. The index for other manufacturing (publishing and logging) moved down 0.4%....

Readmore

Empire State Manufacturing Index Highest in Nearly Three Years

3 DAYS AGO

Business activity grew strongly in New York State, according to firms responding to the August 2017 Empire State Manufacturing Survey. The headline general business conditions index climbed fifteen points to 25.2, its highest level since September 2014. The new orders index rose seven points to 20.6 a...

Readmore

Cobalt-based Alloy 6 Materials and Boiler Feedwater Service

materials_q_and_a_graphicQ: I’ve heard that cobalt-base Alloy 6 materials should not be used in boiler feedwater service. Is this true?

A: Cobalt-chromium Alloy 6 is a very popular material for hard valve trim in applications requiring resistance to sliding wear, erosion and/or cavitation. It’s even successfully used in applications that are somewhat corrosive. However, in some areas of boiler feedwater applications where it would seem Alloy 6 should perform well, problems have been encountered. Here are some theories and facts about the problems:

Alloy 6 is available in cast, wrought and weld overlay forms. The cast material designation is UNS R30006; wrought material is designated UNS R30016, but is commonly called Alloy 6B; the generic AWS designation for hardsurfacing material is CoCr-A (specific designations are ECoCr-A for SMAW electrodes and ERCoCr-A for bare electrodes).

Alloy 6 is a cobalt-chromium-tungsten alloy with approximately 1% carbon. The material consists of a soft, solid solution matrix of cobalt-chromium tungsten surrounding a small percentage of hard, brittle chromium carbides.

Although the carbide phase provides the high hardness (approximately 40 HRC), research has shown that the cobalt-chromium-tungsten matrix is responsible for the alloy’s excellent wear and cavitation resistance. Alloy 6 undergoes a phase transformation (i.e., a change in crystal structure) when highly stressed, such as in a wear or cavitation situation. This phase transformation absorbs some energy that would otherwise cause damage, in effect, reducing the overall level of damage compared with a material that does not exhibit this “shock absorption” property.

Like most corrosion-resistant alloys containing chromium as an alloying element, Alloy 6 achieves corrosion resistance from the formation of a stable chromium oxide passive layer. This passive layer protects the underlying material from reacting with the environment. Certain chemicals can weaken the passive layer, reducing its ability to protect the material from corrosion.

Performance problems with Alloy 6 have been experienced in boiler feedwater applications where the water is treated with hydrazine or some other amine derivative. The problems occur exclusively in regions where the flow velocity is high, indicating that the failure mode is actually erosion-corrosion. Two possible explanations for this phenomenon are that:

1) The amine compounds weaken the oxide passive layer so that it erodes easily. The passive layer is repeatedly eroded away and rebuilt, resulting in accelerated corrosion.

2) The amines prevent the oxide passive layer from reforming after it has eroded initially, thus leaving the alloy unprotected from corrosion. Further erosion-corrosion then occurs at accelerated rates.

Other possible mechanisms for this type of failure may also exist, but the point remains that the alloy is attacked at higher rates than would be expected in an equivalent water application without the presence of the amine compounds.

Studies of returned parts have demonstrated that these attacks definitely correlate to the presence of Alloy 6. The photographs in Figures 1 through 4 were obtained during evaluation of a valve plug with Alloy 6 seat and guide surfaces that suffered erosion- corrosion damage in boiler feedwater. It’s very clear that the damage occurred exclusively in the CoCr-A material, and that the adjacent S31600 material is relatively unaffected, even though it is much softer.

Many failures have occurred in feedwater regulating valves, too. Failures have been reported in special- and standard-trim valves operating at temperatures as low as 300° F (149° C) and pressure drops as low as 100 psi (7 bar). Similar failures have been experienced in tungsten carbide trim in amine-treated feedwater and in ammonia applications when a cobalt binder phase is used.

No amine content, temperature or velocity limits have been established for safe use of Alloy 6 materials in feedwater. Common practice is to avoid the use of cobalt-containing alloys in feedwater service unless the feedwater is known to be compatible with cobalt alloys.

Common alternatives to Alloy 6 include hardened stainless steels such as S41600 (Type 416 SST), S41000 (Type 410 SST), S42000 (Type 420 SST), S44004 (Type 440C SST), or S17400 (17-4 PH SST). In some severely erosive applications, nickel base or iron-base hard-surfacing materials have been used.

  • Latest Post

  • Popular

  • Links

  • Events

Advertisement

Looking for a career in the Valve Industry?

ValveCareers Horiz

To learn more, watch the videos below or visit ValveCareers.com a special initiative of the Valve Manufacturers Association