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Relevance in a Digital Age

Relevance in a Digital Age

The distribution model of the past 50 ye...

Video Game Technology Changing the  Offshore Industry

Video Game Technology Changing the Offshore Industry

One of the most powerful innovations in ...

Reshoring, Robots and What Happens if We Do Bring Jobs Back?

Reshoring, Robots and What Happens if We Do Bring Jobs Back?

While offshoring is painted as the major...

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Industry Headlines

ExxonMobil, SABIC Plan $10B Petrochemical Plant Near Texas Coast

Thursday, 20 April 2017  |  Chris Guy

ExxonMobil Chemical Company and Saudi Arabia Basic Industries Corp. (SABIC) have selected a site in San Patricio County, TX for potential development ...

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Industry Headlines

VanAire Names Steven Soderman CEO, Quality Manager

3 DAYS AGO

Steven Soderman has joined the leadership team of VanAire, Incorporated as CEO and quality manager. Bill VanDeVusse will continue in his role as president having previously filled the positions of both president and CEO.

Soderman has held key quality positions throughout his career most recently fillin...

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Chromatic Industries Adds Two Former Cameron Executives

4 DAYS AGO

Mark Gamber has joined Chromatic Industries as CEO effective April 10, 2017. Wayne Hall will continue in his role as president. Gamber most recently served as vice president of operations at Cameron in its Distributed Valves Group.

Additionally, Mark Cordell has joined Chromatic as a senior advisor. Be...

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ExxonMobil, SABIC Plan $10B Petrochemical Plant Near Texas Coast

3 DAYS AGO

ExxonMobil Chemical Company and Saudi Arabia Basic Industries Corp. (SABIC) have selected a site in San Patricio County, TX for potential development of a jointly owned petrochemical complex on the U.S. Gulf Coast. The proposed project is one of 11 ExxonMobil announced as part of its 10-year, $20 bill...

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Visibility Clears on 2nd Wave of U.S Petrochemical Projects

5 DAYS AGO

The visibility into the second leg of U.S. petrochemical expansions is getting clearer, according to ICIS Chemical Business. While many projects were shelved or in doubt amid the crude oil price decline in 2014-2015, the recent relative stability in oil coupled with a renewed sense of optimism on lo...

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Fed Beige Book Showing Continued Economic Expansion

3 DAYS AGO

Economic activity increased in each of the twelve Federal Reserve Districts between mid-February and the end of March, with the pace of expansion equally split between modest and moderate . In addition, the pickup was evident to varying degrees across economic sectors.

Manufacturing continued to expand...

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IMF Raises Global Growth Forecast to 3.5% This Year

3 DAYS AGO

Global economic activity is picking up with a long-awaited cyclical recovery in investment, manufacturing and trade, according to the IMF’s World Economic Outlook. World growth is expected to rise from 3.1% in 2016 to 3.5% in 2017 and 3.6% in 2018. Stronger activity, expectations of more robust ...

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Wrong Alloy?

materials_q_and_a_graphicQ: My 316 stainless-steel valve is rusty and attracts a magnet. Did I get the wrong alloy?

 

A: Let's answer the second part of the question first. Forged 300-series stainless steels should be non-magnetic. However, cast versions of the 300-series stainless steels-such as CF8 (304), CF3 (304L), CF8M (316), CF3M (316L), CG8M (317), CG3M (317L), CF8C (347), etc.-are all formulated to contain some ferrite. The presence of ferrite makes the alloy less prone to cracking as the hot casting cools in the mold. Weld filler materials are also formulated to contain some ferrite for the same reason. The ferrite makes the material attract a magnet. The exact amount of ferrite, which influences the strength of magnetic attraction, is dependent on the exact chemical composition and the thermal history of the casting. In any event, CF3, CF8, CF3M, CF8M, CG3M, CG8M, and CF8C should all attract a magnet to some degree. In fact, if you have a casting in one of these alloys that doesn't attract a magnet, you should wonder whether something is wrong.

 

Now let's discuss the rusting portion of the question. While the term stainless steel implies that such an alloy is "stainless" or will not rust, the reality is that stainless-steel castings can exhibit a rusty appearance if not processed correctly. The rusty appearance is only superficial surface rust, i.e. iron oxide, and for most applications it is neither a problem nor an indication as to how the equipment will perform in service. However, there are some services where this surface rust is objectionable and special processing is necessary to make sure the stainless-steel castings are truly "stainless." Some of the industries where any rust is undesirable are food and beverage, pharmaceutical, and electronics.

Shot blasting is routinely used by foundries and forge shops to remove burned-in sand, core material, and scale that are formed during casting, forging, and/or heat-treating processes. Steel shot is normally used because it is the quickest and most economical cleaning abrasive. A slight amount of iron contamination remains on the surface of the stainless steel, and may later cause surface discoloration or rusting.

Sand blasting or grit blasting with various abrasives may also be used to clean castings and forgings. If the sand or abrasive was previously used on steel, it may contaminate the stainless-steel surface, which can result in rusting. Therefore, if sand or grit blasting is utilized, the sand or grit should either be new or only used previously for cleaning stainless-steel items.

Pickling, or the more technically correct term acid cleaning, is used to remove iron oxide that formed during the heat treatment of stainless steel or to remove free iron contamination that may have occurred from shot blasting, grit blasting, and/or grinding of stainless- steel castings or forgings. Normally, acid cleaning is only necessary for alloys that do not have sufficient chromium content to prevent oxidation of the surface during heat treatment, such as the 300-series stainless steels. The higher-chromium-content duplex stainless steels do not require acid cleaning unless they are to be used in one of the rust-sensitive industries mentioned above. Pickling is normally done as a last step before machining.

Passivation is the process by which a stainless steel will form a thin, invisible, chemically inactive surface when exposed to air or other oxygen-containing environments. At one time it was considered necessary to apply an oxidizing treatment to stainless steels in order to establish this protective oxide film. It is now accepted that this oxide film will form spontaneously in any oxygen-containing environment provided the surface has been thoroughly acid cleaned, i.e. pickled or descaled. This oxide film is the mechanism by which corrosion-resistant alloys achieve their corrosion resistance. Although a stainless steel is basically self passivating in any oxygen-containing environment, even air, some users of stainless-steel equipment still feel it is necessary to require a separate passivation treatment. If passivation is performed, it is generally done after finish machining.

Acid cleaning and passivation are covered by ASTM specifications A380 and A967. These specifications provide complete details on the acid cleaning and passivation of stainless steels as well as a variety of tests to measure the effectiveness of these processes, including simple wet-dry immersion tests to chemical testing for the detection of free iron. As with any special order requirement, there should be discussions between the manufacturer and customer up front so that everyone is in complete agreement on the processes to be used and how the results will be measured.

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