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Last updateThu, 19 Apr 2018 4pm

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Air Valves in Piping Systems

Air Valves in Piping Systems

Liquid piping systems are prone to colle...

Are Valves from Low-Cost Countries Getting Better?

Are Valves from Low-Cost Countries Getting Better?

The last 25 years have seen standards cr...

Managing the Generation Gap: Much Ado About Nothing?

Managing the Generation Gap: Much Ado About Nothing?

The baby boomer generation was the most ...

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Industry Headlines

Emerson and BlueFin Form Strategic Partnership

Thursday, 19 April 2018  |  Chris Guy

Emerson and BlueFin have signed a working partnership agreement to deliver the Roxar gauge technology to the U.S. Gulf of Mexico (GoM) region. The part...

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Industry Headlines

Emerson and BlueFin Form Strategic Partnership

8 HOURS AGO

Emerson and BlueFin have signed a working partnership agreement to deliver the Roxar gauge technology to the U.S. Gulf of Mexico (GoM) region. The partnership will deliver a combined offering of Emerson's technology coupled with BlueFin's installation services and chemical injection systems.

BlueFin, a...

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Flowserve Expands Partnership with Unisys

1 DAY AGO

Flowserve, a client of Unisys Corporation, will expand its use of the Unisys Stealth microsegmentation solution through a new agreement to implement the solution more broadly across the enterprise. Under the new agreement , Flowserve will increase the number of servers and endpoints protected by Steal...

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OECD Natural Gas Production Up 2.4% in 2017

9 HOURS AGO

An assessment of monthly data shows that in 2017 Organization for Economic Co-operation and Development (OECD) natural gas production grew by 2.4% compared to 2016. This growth was driven by increases in production across all OECD regions, particularly in Asia Oceania (+17.7%), whilst the Americas and...

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Major Trends Changing the Chemical Industry

2 DAYS AGO

“The accelerated globalization of the chemicals market is one of four major trends that we at SAP see shaping the chemical industry through the remainder of 2018 and beyond,” writes Stefan Guertzgen, global senior director for industry solution marketing, chemicals at SAP.

“Amid such ...

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Beige Book: Solid Outlook Despite Tariff Concerns

10 HOURS AGO

Economic activity continued to expand at a modest to moderate pace across the 12 Federal Reserve Districts in March and early April. Outlooks remained positive, but contacts in various sectors including manufacturing, agriculture and transportation expressed concern about the newly imposed and/or prop...

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IMF Predicting Global Economic Upswing

1 DAY AGO

World growth strengthened in 2017 to 3.8%, with a notable rebound in global trade. It was driven by an investment recovery in advanced economies, continued strong growth in emerging Asia, a notable upswing in emerging Europe, and signs of recovery in several commodity exporters. Global growth is exp...

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Wrong Alloy?

materials_q_and_a_graphicQ: My 316 stainless-steel valve is rusty and attracts a magnet. Did I get the wrong alloy?

 

A: Let's answer the second part of the question first. Forged 300-series stainless steels should be non-magnetic. However, cast versions of the 300-series stainless steels-such as CF8 (304), CF3 (304L), CF8M (316), CF3M (316L), CG8M (317), CG3M (317L), CF8C (347), etc.-are all formulated to contain some ferrite. The presence of ferrite makes the alloy less prone to cracking as the hot casting cools in the mold. Weld filler materials are also formulated to contain some ferrite for the same reason. The ferrite makes the material attract a magnet. The exact amount of ferrite, which influences the strength of magnetic attraction, is dependent on the exact chemical composition and the thermal history of the casting. In any event, CF3, CF8, CF3M, CF8M, CG3M, CG8M, and CF8C should all attract a magnet to some degree. In fact, if you have a casting in one of these alloys that doesn't attract a magnet, you should wonder whether something is wrong.

 

Now let's discuss the rusting portion of the question. While the term stainless steel implies that such an alloy is "stainless" or will not rust, the reality is that stainless-steel castings can exhibit a rusty appearance if not processed correctly. The rusty appearance is only superficial surface rust, i.e. iron oxide, and for most applications it is neither a problem nor an indication as to how the equipment will perform in service. However, there are some services where this surface rust is objectionable and special processing is necessary to make sure the stainless-steel castings are truly "stainless." Some of the industries where any rust is undesirable are food and beverage, pharmaceutical, and electronics.

Shot blasting is routinely used by foundries and forge shops to remove burned-in sand, core material, and scale that are formed during casting, forging, and/or heat-treating processes. Steel shot is normally used because it is the quickest and most economical cleaning abrasive. A slight amount of iron contamination remains on the surface of the stainless steel, and may later cause surface discoloration or rusting.

Sand blasting or grit blasting with various abrasives may also be used to clean castings and forgings. If the sand or abrasive was previously used on steel, it may contaminate the stainless-steel surface, which can result in rusting. Therefore, if sand or grit blasting is utilized, the sand or grit should either be new or only used previously for cleaning stainless-steel items.

Pickling, or the more technically correct term acid cleaning, is used to remove iron oxide that formed during the heat treatment of stainless steel or to remove free iron contamination that may have occurred from shot blasting, grit blasting, and/or grinding of stainless- steel castings or forgings. Normally, acid cleaning is only necessary for alloys that do not have sufficient chromium content to prevent oxidation of the surface during heat treatment, such as the 300-series stainless steels. The higher-chromium-content duplex stainless steels do not require acid cleaning unless they are to be used in one of the rust-sensitive industries mentioned above. Pickling is normally done as a last step before machining.

Passivation is the process by which a stainless steel will form a thin, invisible, chemically inactive surface when exposed to air or other oxygen-containing environments. At one time it was considered necessary to apply an oxidizing treatment to stainless steels in order to establish this protective oxide film. It is now accepted that this oxide film will form spontaneously in any oxygen-containing environment provided the surface has been thoroughly acid cleaned, i.e. pickled or descaled. This oxide film is the mechanism by which corrosion-resistant alloys achieve their corrosion resistance. Although a stainless steel is basically self passivating in any oxygen-containing environment, even air, some users of stainless-steel equipment still feel it is necessary to require a separate passivation treatment. If passivation is performed, it is generally done after finish machining.

Acid cleaning and passivation are covered by ASTM specifications A380 and A967. These specifications provide complete details on the acid cleaning and passivation of stainless steels as well as a variety of tests to measure the effectiveness of these processes, including simple wet-dry immersion tests to chemical testing for the detection of free iron. As with any special order requirement, there should be discussions between the manufacturer and customer up front so that everyone is in complete agreement on the processes to be used and how the results will be measured.

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