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Achieving Predictable Valve Performance for Safety Applications

Achieving Predictable Valve Performance for Safety Applications

A focus on having the proper specificati...

Putting Servo Valves Back to Work

Putting Servo Valves Back to Work

Industries as varied as paper production...

Corrosion and Fouling: Is There a Solution?

Corrosion and Fouling: Is There a Solution?

According to a 1998 study released by the ...

Valves with All the Trimmings

Valves with All the Trimmings

The term valve trim has been around for ...

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Industry Headlines

Leading Economic Indicators Rose in January

Friday, 23 February 2018  |  Chris Guy

The Conference Board Leading Economic Index (LEI) for the U.S. increased 1.0% in January to 108.1, following a 0.6% increase in December, and a 0.4% i...

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Valve Positioners Offer Improved Control Valve Performance

Valve Positioners Offer Improved Control Valve Performance

Monday, 19 February 2018  |  David Matherly

From time to time, we are re-posting well-received or particularly valuable articles that have previously run on VALVEMagazine.com so that those who m...

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Industry Headlines

MRC Global Announces Fourth Quarter 2017 Results

3 DAYS AGO

MRC Global’s sales were $903 million for the fourth quarter of 2017, which was 26% higher than the fourth quarter of 2016 and 6% lower than the third quarter of 2017 due to seasonality. As compared to 2016, all sectors increased driven primarily by midstream and upstream.

MRC Global's fourth qu...

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Curtiss-Wright Acquires Dresser-Rand Government Business

4 DAYS AGO

Curtiss-Wright has entered into an agreement to acquire the assets that comprise the Dresser-Rand Government Business (Dresser-Rand), a business unit of Siemens Government Technologies, for $212.5 million in cash.

Dresser-Rand designs and manufactures mission-critical, high-speed rotating equipment sol...

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U.S. Refiners Increasingly Turning to Export Markets

3 DAYS AGO

“U.S. gasoline consumption has leveled off as the stimulus provided by low and falling oil prices between 2014 and 2016 has faded, so refiners are increasingly turning to diesel and customers in emerging markets,” Reuters  reports .

“In geographical terms, the fastest growth in co...

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$900M Power Plant Planned for Indiana

3 DAYS AGO

Vectren Energy Delivery of Indiana is proposing to install an additional 50 megawatts (MW) of universal solar and build an 800 to 900-MW natural gas-fired generation facility in addition to other critical investments that will significantly change the way the company generates power for the region .

Th...

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Leading Economic Indicators Rose in January

1 DAY AGO

The Conference Board Leading Economic Index (LEI) for the U.S. increased 1.0% in January to 108.1, following a 0.6% increase in December, and a 0.4% increase in November.

“The U.S. LEI accelerated further in January and continues to point to robust economic growth in the first half of 2018. Whi...

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IHS Markit Manufacturing Index Rose in February

2 DAYS AGO

U.S. manufacturers reported a strong upturn in business conditions during February, which continued the positive trend seen at the start of 2018. At 55.9, up from 55.5 in January, the seasonally adjusted IHS Markit Flash U.S. Manufacturing Purchasing Managers’ Index (PMI) pointed to the fastes...

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Wrong Alloy?

materials_q_and_a_graphicQ: My 316 stainless-steel valve is rusty and attracts a magnet. Did I get the wrong alloy?

 

A: Let's answer the second part of the question first. Forged 300-series stainless steels should be non-magnetic. However, cast versions of the 300-series stainless steels-such as CF8 (304), CF3 (304L), CF8M (316), CF3M (316L), CG8M (317), CG3M (317L), CF8C (347), etc.-are all formulated to contain some ferrite. The presence of ferrite makes the alloy less prone to cracking as the hot casting cools in the mold. Weld filler materials are also formulated to contain some ferrite for the same reason. The ferrite makes the material attract a magnet. The exact amount of ferrite, which influences the strength of magnetic attraction, is dependent on the exact chemical composition and the thermal history of the casting. In any event, CF3, CF8, CF3M, CF8M, CG3M, CG8M, and CF8C should all attract a magnet to some degree. In fact, if you have a casting in one of these alloys that doesn't attract a magnet, you should wonder whether something is wrong.

 

Now let's discuss the rusting portion of the question. While the term stainless steel implies that such an alloy is "stainless" or will not rust, the reality is that stainless-steel castings can exhibit a rusty appearance if not processed correctly. The rusty appearance is only superficial surface rust, i.e. iron oxide, and for most applications it is neither a problem nor an indication as to how the equipment will perform in service. However, there are some services where this surface rust is objectionable and special processing is necessary to make sure the stainless-steel castings are truly "stainless." Some of the industries where any rust is undesirable are food and beverage, pharmaceutical, and electronics.

Shot blasting is routinely used by foundries and forge shops to remove burned-in sand, core material, and scale that are formed during casting, forging, and/or heat-treating processes. Steel shot is normally used because it is the quickest and most economical cleaning abrasive. A slight amount of iron contamination remains on the surface of the stainless steel, and may later cause surface discoloration or rusting.

Sand blasting or grit blasting with various abrasives may also be used to clean castings and forgings. If the sand or abrasive was previously used on steel, it may contaminate the stainless-steel surface, which can result in rusting. Therefore, if sand or grit blasting is utilized, the sand or grit should either be new or only used previously for cleaning stainless-steel items.

Pickling, or the more technically correct term acid cleaning, is used to remove iron oxide that formed during the heat treatment of stainless steel or to remove free iron contamination that may have occurred from shot blasting, grit blasting, and/or grinding of stainless- steel castings or forgings. Normally, acid cleaning is only necessary for alloys that do not have sufficient chromium content to prevent oxidation of the surface during heat treatment, such as the 300-series stainless steels. The higher-chromium-content duplex stainless steels do not require acid cleaning unless they are to be used in one of the rust-sensitive industries mentioned above. Pickling is normally done as a last step before machining.

Passivation is the process by which a stainless steel will form a thin, invisible, chemically inactive surface when exposed to air or other oxygen-containing environments. At one time it was considered necessary to apply an oxidizing treatment to stainless steels in order to establish this protective oxide film. It is now accepted that this oxide film will form spontaneously in any oxygen-containing environment provided the surface has been thoroughly acid cleaned, i.e. pickled or descaled. This oxide film is the mechanism by which corrosion-resistant alloys achieve their corrosion resistance. Although a stainless steel is basically self passivating in any oxygen-containing environment, even air, some users of stainless-steel equipment still feel it is necessary to require a separate passivation treatment. If passivation is performed, it is generally done after finish machining.

Acid cleaning and passivation are covered by ASTM specifications A380 and A967. These specifications provide complete details on the acid cleaning and passivation of stainless steels as well as a variety of tests to measure the effectiveness of these processes, including simple wet-dry immersion tests to chemical testing for the detection of free iron. As with any special order requirement, there should be discussions between the manufacturer and customer up front so that everyone is in complete agreement on the processes to be used and how the results will be measured.

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