06272017Tue
Last updateTue, 27 Jun 2017 5pm

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Lubricants: Always Important—Sometimes Essential

Lubricants: Always Important—Sometimes Essential

Most valve professionals take more notic...

Why Air Valves are Needed in Water Applications

Why Air Valves are Needed in Water Applications

Air valves are hydromechanical devices d...

Achieving Profitability Through Maintenance Management

Achieving Profitability Through Maintenance Management

One of the distinctions between maintena...

Control Valve Positioner Performance Diagnostics

Control Valve Positioner Performance Diagnostics

There has been discussion for some years...

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Industry Headlines

Emerson in Talks to Acquire Software Company Paradigm Ltd.

-1 DAYS AGO

According to Bloomberg , Emerson is in talks to acquire software company Paradigm Ltd. for approximately $1.5 billion.

“Paradigm specializes in seismic data interpretation and imaging equipment to help oil and gas companies know where to drill. The logic of such a deal seems sound and will help Eme...

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VMA Members Lead MDM Top Industrial PVF Distributors List

23 HOURS AGO

Modern Distribution Management (MDM) recently published its Top Distributors list for 2017. Four of the top 5 distributors in the Industrial PVF category ; MRC Global, NOW Inc., Wolseley Industrial Group and FloWorks International; are currently VMA members.

“While oil & gas markets have start...

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Mountain Valley Pipeline Gets Environmental Approval

-1 DAYS AGO

The Federal Energy Regulatory Commission (FERC) determined that construction and operation of the Mountain Valley Pipeline would result in some adverse environmental impacts, but the majority of these impacts would be reduced to less-than-significant levels. This determination is based on a review o...

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Delta Chemical Plant Planned for Houston Area

18 HOURS AGO

Braskem will commit up to $675 million in investment capital towards the design and construction of a new facility, named Delta, located next to Braskem's existing production facilities. Construction is expected to begin mid-summer, with the final phase of main construction targeted for the first qu...

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U.S. Durable Goods Orders Fell the Most in 18 Months

-1 DAYS AGO

New orders for manufactured durable goods in May decreased $2.5 billion or 1.1% to $228.2 billion, the U.S. Department of Commerce announced. This decrease, down two consecutive months, followed a 0.9% April decrease. Excluding transportation, new orders increased 0.1%. Excluding defense, new orders...

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Texas Manufacturers See 12th Consecutive Month of Growth

-1 DAYS AGO

Texas factory activity increased in June, according to the Texas Manufacturing Outlook Survey. The production index, a key measure of state manufacturing conditions, fell 11 points to 12.3, indicating output grew but at a slower pace than in May.

Other measures of current manufacturing activity also i...

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Wrong Alloy?

materials_q_and_a_graphicQ: My 316 stainless-steel valve is rusty and attracts a magnet. Did I get the wrong alloy?

 

A: Let's answer the second part of the question first. Forged 300-series stainless steels should be non-magnetic. However, cast versions of the 300-series stainless steels-such as CF8 (304), CF3 (304L), CF8M (316), CF3M (316L), CG8M (317), CG3M (317L), CF8C (347), etc.-are all formulated to contain some ferrite. The presence of ferrite makes the alloy less prone to cracking as the hot casting cools in the mold. Weld filler materials are also formulated to contain some ferrite for the same reason. The ferrite makes the material attract a magnet. The exact amount of ferrite, which influences the strength of magnetic attraction, is dependent on the exact chemical composition and the thermal history of the casting. In any event, CF3, CF8, CF3M, CF8M, CG3M, CG8M, and CF8C should all attract a magnet to some degree. In fact, if you have a casting in one of these alloys that doesn't attract a magnet, you should wonder whether something is wrong.

 

Now let's discuss the rusting portion of the question. While the term stainless steel implies that such an alloy is "stainless" or will not rust, the reality is that stainless-steel castings can exhibit a rusty appearance if not processed correctly. The rusty appearance is only superficial surface rust, i.e. iron oxide, and for most applications it is neither a problem nor an indication as to how the equipment will perform in service. However, there are some services where this surface rust is objectionable and special processing is necessary to make sure the stainless-steel castings are truly "stainless." Some of the industries where any rust is undesirable are food and beverage, pharmaceutical, and electronics.

Shot blasting is routinely used by foundries and forge shops to remove burned-in sand, core material, and scale that are formed during casting, forging, and/or heat-treating processes. Steel shot is normally used because it is the quickest and most economical cleaning abrasive. A slight amount of iron contamination remains on the surface of the stainless steel, and may later cause surface discoloration or rusting.

Sand blasting or grit blasting with various abrasives may also be used to clean castings and forgings. If the sand or abrasive was previously used on steel, it may contaminate the stainless-steel surface, which can result in rusting. Therefore, if sand or grit blasting is utilized, the sand or grit should either be new or only used previously for cleaning stainless-steel items.

Pickling, or the more technically correct term acid cleaning, is used to remove iron oxide that formed during the heat treatment of stainless steel or to remove free iron contamination that may have occurred from shot blasting, grit blasting, and/or grinding of stainless- steel castings or forgings. Normally, acid cleaning is only necessary for alloys that do not have sufficient chromium content to prevent oxidation of the surface during heat treatment, such as the 300-series stainless steels. The higher-chromium-content duplex stainless steels do not require acid cleaning unless they are to be used in one of the rust-sensitive industries mentioned above. Pickling is normally done as a last step before machining.

Passivation is the process by which a stainless steel will form a thin, invisible, chemically inactive surface when exposed to air or other oxygen-containing environments. At one time it was considered necessary to apply an oxidizing treatment to stainless steels in order to establish this protective oxide film. It is now accepted that this oxide film will form spontaneously in any oxygen-containing environment provided the surface has been thoroughly acid cleaned, i.e. pickled or descaled. This oxide film is the mechanism by which corrosion-resistant alloys achieve their corrosion resistance. Although a stainless steel is basically self passivating in any oxygen-containing environment, even air, some users of stainless-steel equipment still feel it is necessary to require a separate passivation treatment. If passivation is performed, it is generally done after finish machining.

Acid cleaning and passivation are covered by ASTM specifications A380 and A967. These specifications provide complete details on the acid cleaning and passivation of stainless steels as well as a variety of tests to measure the effectiveness of these processes, including simple wet-dry immersion tests to chemical testing for the detection of free iron. As with any special order requirement, there should be discussions between the manufacturer and customer up front so that everyone is in complete agreement on the processes to be used and how the results will be measured.

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