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Human Factors Can Cause a Disaster—or Prevent One

Human Factors Can Cause a Disaster—or Prevent One

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Improving Valve Sealing Performance and Reliability

Improving Valve Sealing Performance and Reliability

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A Primer on Fugitive Emissions

A Primer on Fugitive Emissions

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Emerson Expanding Mississippi Facility

4 DAYS AGO

Emerson plans on delivering $500,000 in new equipment to its facility in Sherman, MS. Because of this investment , and its promise of new jobs for the region, the Sherman Economic Development Corp. has approved $150,000 in grants for Emerson.

"We have a relatively new Fisher product that will be reloca...

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REXA and CCC Form Joint Initiative

4 DAYS AGO

REXA and Compressor Controls Corporation (CCC) have formed a joint initiative to modernize steam turbine controls for enhanced performance based upon each company’s core competency.

There are more than 10,000 turbomachinery trains worldwide powered by CCC. By upgrading mechanical and hydraulic go...

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LNG Exports Expected to Drive Growth in U.S. Natural Gas Trade

9 HOURS AGO

The U.S. is expected to become a net exporter of natural gas on an average annual basis by 2018, according to the recently released Annual Energy Outlook 2017 (AEO2017). The transition to net exporter is driven by declining pipeline imports, growing pipeline exports, and increasing exports of liquefie...

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Energy Transfer Partners Building New NGL Fractionation Facility

12 HOURS AGO

Energy Transfer Partners’ subsidiary, Lone Star NGL LLC, will construct a fifth natural gas liquids (NGL) fractionation facility at Mont Belvieu, TX. The construction of Fractionator V is a result of the tremendous production growth in the Delaware and Permian Basins.

Fractionator V, including NG...

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Kansas City Fed Survey Shows Regional Manufacturing Jump

12 HOURS AGO

According to Chad Wilkerson, vice president and economist at the Kansas City Fed, the district’s February Manufacturing Survey revealed that manufacturing activity expanded further with continued strong expectations . The Federal Reserve Bank of Kansas City serves the tenth Federal Reserve Distr...

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U.S. Private Sector Growth Slows from January’s 14-Month Peak

4 DAYS AGO

At 54.3 in February, the seasonally adjusted Markit Flash U.S. Composite PMI Output Index dropped from 55.8 in January but remained above the 50.0 no-change value for the twelfth consecutive month. The latest reading signaled that private sector output growth moderated from the 14-month high recorded ...

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Wrong Alloy?

materials_q_and_a_graphicQ: My 316 stainless-steel valve is rusty and attracts a magnet. Did I get the wrong alloy?

 

A: Let's answer the second part of the question first. Forged 300-series stainless steels should be non-magnetic. However, cast versions of the 300-series stainless steels-such as CF8 (304), CF3 (304L), CF8M (316), CF3M (316L), CG8M (317), CG3M (317L), CF8C (347), etc.-are all formulated to contain some ferrite. The presence of ferrite makes the alloy less prone to cracking as the hot casting cools in the mold. Weld filler materials are also formulated to contain some ferrite for the same reason. The ferrite makes the material attract a magnet. The exact amount of ferrite, which influences the strength of magnetic attraction, is dependent on the exact chemical composition and the thermal history of the casting. In any event, CF3, CF8, CF3M, CF8M, CG3M, CG8M, and CF8C should all attract a magnet to some degree. In fact, if you have a casting in one of these alloys that doesn't attract a magnet, you should wonder whether something is wrong.

 

Now let's discuss the rusting portion of the question. While the term stainless steel implies that such an alloy is "stainless" or will not rust, the reality is that stainless-steel castings can exhibit a rusty appearance if not processed correctly. The rusty appearance is only superficial surface rust, i.e. iron oxide, and for most applications it is neither a problem nor an indication as to how the equipment will perform in service. However, there are some services where this surface rust is objectionable and special processing is necessary to make sure the stainless-steel castings are truly "stainless." Some of the industries where any rust is undesirable are food and beverage, pharmaceutical, and electronics.

Shot blasting is routinely used by foundries and forge shops to remove burned-in sand, core material, and scale that are formed during casting, forging, and/or heat-treating processes. Steel shot is normally used because it is the quickest and most economical cleaning abrasive. A slight amount of iron contamination remains on the surface of the stainless steel, and may later cause surface discoloration or rusting.

Sand blasting or grit blasting with various abrasives may also be used to clean castings and forgings. If the sand or abrasive was previously used on steel, it may contaminate the stainless-steel surface, which can result in rusting. Therefore, if sand or grit blasting is utilized, the sand or grit should either be new or only used previously for cleaning stainless-steel items.

Pickling, or the more technically correct term acid cleaning, is used to remove iron oxide that formed during the heat treatment of stainless steel or to remove free iron contamination that may have occurred from shot blasting, grit blasting, and/or grinding of stainless- steel castings or forgings. Normally, acid cleaning is only necessary for alloys that do not have sufficient chromium content to prevent oxidation of the surface during heat treatment, such as the 300-series stainless steels. The higher-chromium-content duplex stainless steels do not require acid cleaning unless they are to be used in one of the rust-sensitive industries mentioned above. Pickling is normally done as a last step before machining.

Passivation is the process by which a stainless steel will form a thin, invisible, chemically inactive surface when exposed to air or other oxygen-containing environments. At one time it was considered necessary to apply an oxidizing treatment to stainless steels in order to establish this protective oxide film. It is now accepted that this oxide film will form spontaneously in any oxygen-containing environment provided the surface has been thoroughly acid cleaned, i.e. pickled or descaled. This oxide film is the mechanism by which corrosion-resistant alloys achieve their corrosion resistance. Although a stainless steel is basically self passivating in any oxygen-containing environment, even air, some users of stainless-steel equipment still feel it is necessary to require a separate passivation treatment. If passivation is performed, it is generally done after finish machining.

Acid cleaning and passivation are covered by ASTM specifications A380 and A967. These specifications provide complete details on the acid cleaning and passivation of stainless steels as well as a variety of tests to measure the effectiveness of these processes, including simple wet-dry immersion tests to chemical testing for the detection of free iron. As with any special order requirement, there should be discussions between the manufacturer and customer up front so that everyone is in complete agreement on the processes to be used and how the results will be measured.

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