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How to Choose the Best Rapid Prototyping Method

How to Choose the Best Rapid Prototyping Method

As new products are designed, including ...

Monitoring Valve Health via the Internet

Monitoring Valve Health via the Internet

Most valve end users are already using s...

Valves in Oxygen Service

Valves in Oxygen Service

In his presentation at VMA’s 2017 ...

Thermal Spray Coating

Thermal Spray Coating

Q: What are the pros and cons of us...

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Industry Headlines

TAQA Awards Schlumberger EPCIC Contract for Otter Field

Wednesday, 26 July 2017  |  Chris Guy

OneSubsea, a Schlumberger company, has been awarded an engineering, procurement, construction, installation and commissioning (EPCIC) contract for a s...

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The Actuation Selection Process

The Actuation Selection Process

Tuesday, 25 July 2017  |  Carlos Gamero

A common misconception in our industry is that actuating a valve is as simple as putting the most cost-efficient actuator on top of your valve of choi...

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Industry Headlines

TAQA Awards Schlumberger EPCIC Contract for Otter Field

12 HOURS AGO

OneSubsea, a Schlumberger company, has been awarded an engineering, procurement, construction, installation and commissioning (EPCIC) contract for a subsea multiphase boosting system by TAQA for the Otter field in the UK North Sea. OneSubsea leverages Cameron flow control, process technologies and m...

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Crane Co. Reports Second Quarter Results

1 DAY AGO

Crane Co. reported second quarter 2017 earnings of $1.14 per diluted share, compared to $1.15 per share in the second quarter of 2016. Excluding Special Items, second quarter 2017 earnings per diluted share were $1.17, compared to $1.21 per share in the second quarter of 2016.

Second quarter 2017 sale...

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Shale Sector to Be Cash Flow Positive by 2020

12 HOURS AGO

The tight oil sector has struggled to generate positive cash flow since 2010. Last year, only one company in the sector posted positive cash flow. But there is light at the end of the tunnel. Wood Mackenzie’s new report " When will tight oil make money? " calculates that the five largest tight oil...

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U.S. Chemical Production Moved Higher in June

1 DAY AGO

According to the American Chemistry Council (ACC), the U.S. Chemical Production Regional Index (U.S. CPRI) edged higher by 0.3% in June, following a 0.3% gain in May, and a 0.4% decline in April, as measured on a three-month moving average (3MMA) basis. During June, output grew in all regions except t...

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U.S. Consumer Confidence Rebounds in July

18 HOURS AGO

The Conference Board Consumer Confidence Index, which had declined marginally in June (a downward revision), improved in July . The Index now stands at 121.1, up from 117.3 in June. The Present Situation Index increased from 143.9 to 147.8, while the Expectations Index rose from 99.6 last month to 103...

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IHS Market PMI Index Reached Four-Month High in July

1 DAY AGO

July data revealed a further acceleration in business activity growth across the U.S. private sector. At 54.2, up from 53.9 in June, the seasonally adjusted IHS Markit Flash U.S. Composite PMI Output Index signaled the strongest rate of expansion since January.

The pickup in business activity growth ...

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Choosing the Right Fasteners

materials_q_and_a_graphicQ: What do I need to know to choose the right fasteners for my valves?

A: Choosing the proper fastener alloy is one of the most important considerations for reliable long-term operation of valves and other chemical process equipment. The easy part is choosing a fastener with adequate strength whereas selecting fasteners with the necessary corrosion resistance is somewhat more difficult. Choosing fasteners for their general corrosion resistance is certainly an obvious consideration, but it is sometimes even more important to use and specify fastener materials that will be resistant to the various forms of environmental stress corrosion cracking (SCC). Therefore, in certain environments it may be necessary to choose a bolt material that will experience some general corrosion but will provide adequate resistance to stress corrosion cracking. The logic behind this practice is that general corrosion is visually evident and with proper preventative maintenance, general corrosion can be seen and fasteners replaced as necessary. On the other hand, stress corrosion cracking is rarely visually apparent and often occurs without warning. When it does, then a serious valve failure is likely.

There are several forms of stress corrosion cracking that we need to be aware of such as chloride SCC, hydrogen sulfide HSSC, caustic embrittlement and liquid metal embrittlement. Because austenitic stainless-steel fasteners like ASTM A193 grade B8 provide good general corrosion resistance, they are commonly requested. However, one must exercise care as to their use if there is reason to believe that chloride SCC may be an issue. Chlorides as well as other halogens such as fluorides may be present in many CPI plants, and they can be the catalyst for SCC of austenitic stainless steels like 304 or 316. Chlorides are also present in the environment of seacoast plants. Because marine environments are very corrosive to carbon steels, many plants request stainless-steel fasteners but this may lead to the potential for a serious failure due to chloride SCC. Therefore, for marine environments or other chloride-containing services, alloy steel fasteners are preferred. In order to reduce their susceptibility to general corrosion, alloy steel fasteners like grade B7 are usually provided with some type of protective coating such as zinc or cadmium plating. Unfortunately, this can lead to another form of environmental stress cracking known as liquid metal embrittlement (LME), or a related failure mode, solid metal induced embrittlement (SMIE).

Zinc and cadmium plating are commonly used to provide galvanic protection to carbon steel fasteners so they will have an acceptable general corrosion rate. This is a useful practice for moderate temperatures but at elevated temperatures either LME or SMIE may occur. LME is the brittle failure of a normally ductile metal when in contact with a thin film of liquid metal and stressed in tension. The source of the thin film of liquid metal is the cadmium or zinc used for galvanic protection of steel from general corrosion. Cadmium and zinc have relatively low melting points so when plated fasteners are used near or above their melting point LME is possible. SMIE is similar, but occurs below the melting point of the embrittling metal. Prevention of LME and SMIE can be accomplished by avoiding plated fasteners above certain maximum temperatures. According to the available literature, this temperature is 370º F (188º C) for cadmium and 489º F (254º C) for zinc-plated alloy steel. Due to other environmental concerns, cadmium is not used much today but it is still available so you need to be sure of what type of plated fasteners you are getting from your supplier. I know of one case where zinc-plated fasteners were ordered but the supplier substituted some cadmium-plated fasteners by mistake. Since the service temperature was above 370° F (188° C), an LME/SMIE failure resulted.

Another common concern about fastener selection is hydrogen sulfide stress cracking, HSSC. Most metals are susceptible to stress cracking if exposed to hydrogen sulfide, and fasteners that are high strength and highly stressed are very susceptible to HSSC. Therefore, the NACE specifications, MR0103 and ISO 15156, which deal with hydrogen sulfide services, state that if fasteners are exposed to hydrogen sulfide they need to be made of certain alloys. For MR0103 those are ASTM A193 grades B7M or B8MA class 1A and A320 grade L7M. For ISO 15156 the recommend fasteners are A193 grade B7M or A320 grade L7M.

Some other services that can cause SCC with certain fasteners are caustic compounds and hydrofluoric acid. Fortunately, most atmospheric environments do not contain the stress cracking agents discussed here but if there is any chance of exposure, give careful consideration to the selection of fasteners. Choosing the right fastener is rather complex so use a fastener supplier that understands these issues or consult with a corrosion engineer.

Thomas Spence is director of materials engineering for Flowserve Corp. (www.flowserve.com), Dayton, OH. Reach him at This email address is being protected from spambots. You need JavaScript enabled to view it..

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