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Last updateTue, 28 Mar 2017 8pm

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Valves Help Enable Net-Zero Water Use

Valves Help Enable Net-Zero Water Use

With drought and climate change affecting ...

Valve Selection in Pulp and Paper Operations

Valve Selection in Pulp and Paper Operations

Over the centuries, the pulp and paper i...

How to Improve Control Valve Performance with Positioners

How to Improve Control Valve Performance with Positioners

As the final control element in most pro...

VMA Technical Event: Engineering Valves in the Extreme

VMA Technical Event: Engineering Valves in the Extreme

While much the 2017 VMA Technical Semina...

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Industry Headlines

Colorado Seeing Surge in Oil & Gas Investments

Tuesday, 28 March 2017  |  Chris Guy

“Drilling applications and investments by oil and gas companies are surging in Colorado after crude prices partially rebounded from their collap...

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Industry Headlines

Emerson Opens Second Additive Manufacturing Center

20 HOURS AGO

With the goal of spurring innovation to address customers’ engineering design challenges and accelerating speed to market for new, rigorously-tested products, Emerson opened an advanced additive manufacturing center at its Singapore campus. This is Emerson’s second location to have additiv...

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GE Oil & Gas Expands with New Sub Saharan Africa Facility

4 DAYS AGO

GE Oil & Gas opened a new facility in Takoradi Port, Ghana, expanding its global footprint and supporting local investment. The facility, which will be the primary service center for deep-water offshore projects in Ghana, has a 1,600 square meter indoor test area with capability for testing thre...

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Colorado Seeing Surge in Oil & Gas Investments

59 MINS AGO

“Drilling applications and investments by oil and gas companies are surging in Colorado after crude prices partially rebounded from their collapse in recent years, pushing the industry deeper into residential communities largely unaccustomed to drilling,” the Associated Press is reporting .

&...

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U.S. Specialty Chemicals Markets Accelerated in February

19 HOURS AGO

The American Chemistry Council (ACC) reported that U.S. specialty chemicals market volumes rose a strong 0.6% in February. This follows an upwardly revised 0.4% gain in January. Volumes have generally been moving up since May. All changes in the data are reported on a three-month moving average (3MMA)...

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Four Out of Ten Jobs Could be Lost to Automation by 2021

1 HOUR AGO

Automation is the new norm across sectors and will affect the bottom of pyramid so much so that four out of every 10 jobs globally would be lost due to this by 2021, experts say. As automation adoption increases, all high transaction and labor intensive jobs will take a hit. According to PeopleStrong...

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U.S. Durable Goods Orders Rose 1.7% in February

1 DAY AGO

New orders for manufactured durable goods in February increased $3.9 billion or 1.7% to $235.4 billion, the U.S. Department of Commerce announced . This increase, up two consecutive months, followed a 2.3% January increase. Excluding transportation, new orders increased 0.4%. Excluding defense, new or...

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Multi-colored Stain on Valves

materials_q_and_a_graphicQ: I am handling high purity-water and keep getting a multi-colored stain on my valves and other equipment. What is this, and how can I prevent it?

A: You are describing a phenomenon called "rouging," a term that pertains to the multi-colored stain you are seeing. Rouging is a problem that is seen primarily in high-purity water applications or steam. Though more commonly associated with the pharmaceutical and electronics industries, it can occur most anywhere. At the lower temperatures rouge is red or yellowish in appearance, but in high-temperature steam it will be dark gray or black. The FDA has not made any formal opinion about rouging, but pharmaceutical companies are concerned about contamination of their products so they go to great lengths to prevent it and to clean their systems when it occurs-incurring undesired downtime and expense.

The mechanism of rouging is still not fully understood and as a result there are some myths and misconceptions about what it is and how to prevent it. Essentially, rouge is a form of rust, i.e., iron oxide, but different than the heavy rust seen when stainless steel is not cleaned properly after heat treatment or welding. While normal rust is a result of improper cleaning during manufacture, rouge is a much thinner layer that occurs when perfectly cleaned stainless steel reacts with high-purity water environments. Rouge seems to be more prevalent at temperatures in excess or 60° C.

We know that stainless steels achieve their corrosion resistance by developing a very thin microscopic chromium oxide layer. The general consensus about rouging is that certain services, such as high purity water with very low oxygen content, dissolve this protective layer and allow the stainless steel to resume corroding. This corrosion is then responsible for the staining we call rouging. These stains have been analyzed as being various types of iron oxide as well as containing traces of chromium and nickel.

While mainly an aesthetics problem, most people still want to prevent rouge in their systems. One commonly held belief is that the ferrite phase in cast stainless steels or welds causes rouging, and purchasers of valves and other equipment frequently impose strict limits on the ferrite content of cast stainless steels. Since wrought stainless steels with no ferrite also experience rouging, it doesn't appear that ferrite is the culprit.

A study conducted by AvestaPolarit1, found that the water's gas content and a metal's surface finish were influential for rouging. Basically, water with high oxygen and low carbon dioxide content was less likely to cause rouging as were electro-polished surfaces of the metal components. This study also found no significant correlation for the different alloy grades, including duplex stainless steels with their high ferrite content.

Since most people find rouge objectionable in their systems, much attention has been given to its removal. Various acids and chelates are used to clean systems of rouge, but these can leave behind their own contaminates or films. In addition, if acid exposure is not controlled closely, the acid can etch the metal surfaces thus destroying the expensive electro-polished surfaces. Therefore, the most effective way to prevent rouge is by somehow introducing sufficient oxygen to the system, which helps maintain the protective chromium oxide layer.

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