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Monitoring Valve Health via the Internet

Monitoring Valve Health via the Internet

Most valve end users are already using s...

Valves in Oxygen Service

Valves in Oxygen Service

In his presentation at VMA’s 2017 ...

Thermal Spray Coating

Thermal Spray Coating

Q: What are the pros and cons of us...

Ball Valve Repair 101

Ball Valve Repair 101

From time to time, we are re-posting wel...

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Industry Headlines

LyondellBasell to Build the World's Largest PO/TBA Plant

Friday, 21 July 2017  |  Chris Guy

LyondellBasell has made the final investment decision to build the world's largest propylene oxide (PO) and tertiary butyl alcohol (TBA) plant in the ...

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How to Choose the Best Rapid Prototyping Method

How to Choose the Best Rapid Prototyping Method

Tuesday, 18 July 2017  |  Kate Kunkel

As new products are designed, including valve bodies and the parts that comprise the finished valve, prototypes must be created. How that is achieved ...

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Industry Headlines

Badger Alloys Joins VMA as Associate Member

4 DAYS AGO

This week the Valve Manufacturers Association (VMA) welcomes Badger Alloys as an official associate supplier member. This is VMA’s fourth new member in 2017.

Located in the heart of Milwaukee and founded in 1966, Badger Alloys offers single source capabilities for custom castings. The company pou...

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Thermodyn Joins VMA as Associate Member

4 DAYS AGO

This week the Valve Manufacturers Association (VMA) welcomes Thermodyn Corporation as an official associate supplier member. This is VMA's third new member in 2017.

In 1979, Thermodyn began business with the dual purpose of selling A.W. Chesterton products and manufacturing high-temperature elastomers ...

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LyondellBasell to Build the World's Largest PO/TBA Plant

1 DAY AGO

LyondellBasell has made the final investment decision to build the world's largest propylene oxide (PO) and tertiary butyl alcohol (TBA) plant in the Houston area. The project is estimated to cost approximately $2.4 billion, representing the single-largest capital investment in the company's history...

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EPA Selects Projects for Water Infrastructure Loans

2 DAYS AGO

The EPA is inviting 12 projects in nine states to apply for Water Infrastructure Finance and Innovation Act (WIFIA) loans. These potential applicants were selected from a group of projects that represent large and small communities from across the U.S. that submitted letters of interest to EPA in Ap...

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Leading Economic Indicators Increased in June

1 DAY AGO

The Conference Board Leading Economic Index (LEI) for the U.S. increased 0.6% in June to 127.8 (2010 = 100), following a 0.2% increase in May, and a 0.2% increase in April.

“The U.S. LEI rose sharply in June, pointing to continued growth in the U.S. economy and perhaps even a moderate improvement...

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U.S. Jobless Claims Fall to Near Five-Month Low

2 DAYS AGO

In the week ending July 15, the advance figure for seasonally adjusted initial claims was 233,000, a decrease of 15,000 from the previous week's revised level. The previous week's level was revised up by 1,000 from 247,000 to 248,000. The 4-week moving average was 243,750, a decrease of 2,250 from t...

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Multi-colored Stain on Valves

materials_q_and_a_graphicQ: I am handling high purity-water and keep getting a multi-colored stain on my valves and other equipment. What is this, and how can I prevent it?

A: You are describing a phenomenon called "rouging," a term that pertains to the multi-colored stain you are seeing. Rouging is a problem that is seen primarily in high-purity water applications or steam. Though more commonly associated with the pharmaceutical and electronics industries, it can occur most anywhere. At the lower temperatures rouge is red or yellowish in appearance, but in high-temperature steam it will be dark gray or black. The FDA has not made any formal opinion about rouging, but pharmaceutical companies are concerned about contamination of their products so they go to great lengths to prevent it and to clean their systems when it occurs-incurring undesired downtime and expense.

The mechanism of rouging is still not fully understood and as a result there are some myths and misconceptions about what it is and how to prevent it. Essentially, rouge is a form of rust, i.e., iron oxide, but different than the heavy rust seen when stainless steel is not cleaned properly after heat treatment or welding. While normal rust is a result of improper cleaning during manufacture, rouge is a much thinner layer that occurs when perfectly cleaned stainless steel reacts with high-purity water environments. Rouge seems to be more prevalent at temperatures in excess or 60° C.

We know that stainless steels achieve their corrosion resistance by developing a very thin microscopic chromium oxide layer. The general consensus about rouging is that certain services, such as high purity water with very low oxygen content, dissolve this protective layer and allow the stainless steel to resume corroding. This corrosion is then responsible for the staining we call rouging. These stains have been analyzed as being various types of iron oxide as well as containing traces of chromium and nickel.

While mainly an aesthetics problem, most people still want to prevent rouge in their systems. One commonly held belief is that the ferrite phase in cast stainless steels or welds causes rouging, and purchasers of valves and other equipment frequently impose strict limits on the ferrite content of cast stainless steels. Since wrought stainless steels with no ferrite also experience rouging, it doesn't appear that ferrite is the culprit.

A study conducted by AvestaPolarit1, found that the water's gas content and a metal's surface finish were influential for rouging. Basically, water with high oxygen and low carbon dioxide content was less likely to cause rouging as were electro-polished surfaces of the metal components. This study also found no significant correlation for the different alloy grades, including duplex stainless steels with their high ferrite content.

Since most people find rouge objectionable in their systems, much attention has been given to its removal. Various acids and chelates are used to clean systems of rouge, but these can leave behind their own contaminates or films. In addition, if acid exposure is not controlled closely, the acid can etch the metal surfaces thus destroying the expensive electro-polished surfaces. Therefore, the most effective way to prevent rouge is by somehow introducing sufficient oxygen to the system, which helps maintain the protective chromium oxide layer.

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