06252016Sat
Last updateFri, 24 Jun 2016 2pm

i

Problem-Driven Innovation

Problem-Driven Innovation

Developing Alternative Technology to Imp...

Valve Repair Takes Center Stage in Houston

Valve Repair Takes Center Stage in Houston

Attendees gathered June 2-3 in Houston t...

What Internal Best Practices Can Do for Valve Selection

What Internal Best Practices Can Do for Valve Selection

As time goes by, technology moves forwar...

Subscribe

SUBSCRIBE

•  Digital magazine

•  Print magazine

•  VALVE eNews

Read the latest issue of VALVE Magazine

BUYERS GUIDE 300x220

New Products

  • ja-news-2
  • ja-news-3

Industry Headlines

Advertisement
i

Web Only

Problem-Driven Innovation

Problem-Driven Innovation

Monday, 20 June 2016  |  Mark A. Lobo, P.E.

Developing Alternative Technology to Improve Product Performance

Industrial product engineering teaches us to understand the difference between problem...

Readmore

Loading...

Industry Headlines

Curtiss-Wright Awarded Contracts for U.S. Naval Defense Platforms

2 DAYS AGO

Curtiss-Wright announced that it has been awarded contracts valued in excess of $80 million to provide valves for the U.S. Navy’s Virginia-class submarines and Ford-class aircraft carriers. The awards were received from Bechtel Plant Machinery, Inc. and General Dynamics Electric Boat Division ...

Readmore

DeZURIK Adds Dedicated Clean Room to Sartell Plant

3 DAYS AGO

In order to ensure proper cleaning procedures are performed on valves intended for oxygen, ozone, chlorine, hydrogen peroxide, isocyanate and other applications, DeZURIK has constructed a new dedicated clean room within its Sartell, MN manufacturing plant.

Operated by trained cleaning technicians, DeZU...

Readmore

Global Upstream Spending Slashed by $1 Trillion

1 DAY AGO

Global upstream development spending from 2015 to 2020 has been cut by 22% or $740 billion since the oil price started to drop two years ago, according Wood Mackenzie's research . When you include cuts to conventional exploration investment, the figure increases to just over $1 trillion. Expect to see...

Readmore

EPA Bans Fracking Wastewater Disposal at Public Treatment Plants

4 DAYS AGO

The EPA has finalized a rule establishing pretreatment standards for discharges of wastewater from onshore unconventional oil and gas (UOG) extraction facilities to municipal sewage treatment plants (also known as publicly owned treatment works, or POTWs). The rule is designed to prevent the discharge...

Readmore

U..S. Durable Goods Orders Down 2.2% in May

1 DAY AGO

New orders for manufactured durable goods in May decreased $5.3 billion or 2.2% to $230.7 billion, the Commerce Department announced today. This decrease , down following two consecutive monthly increases, followed a 3.3% April increase. Excluding transportation, new orders decreased 0.3%. Excluding d...

Readmore

Federal Judge Halts New BLM Fracking Rules

2 DAYS AGO

“The Obama administration will fight a federal judge’s ruling overturning its effort to regulate hydraulic fracturing on public lands,” Bloomberg reports . The White House says they will take the case to the U.S. Court of Appeals.

“The ruling, issued late Tuesday by Wyoming-based...

Readmore

Multi-colored Stain on Valves

materials_q_and_a_graphicQ: I am handling high purity-water and keep getting a multi-colored stain on my valves and other equipment. What is this, and how can I prevent it?

A: You are describing a phenomenon called "rouging," a term that pertains to the multi-colored stain you are seeing. Rouging is a problem that is seen primarily in high-purity water applications or steam. Though more commonly associated with the pharmaceutical and electronics industries, it can occur most anywhere. At the lower temperatures rouge is red or yellowish in appearance, but in high-temperature steam it will be dark gray or black. The FDA has not made any formal opinion about rouging, but pharmaceutical companies are concerned about contamination of their products so they go to great lengths to prevent it and to clean their systems when it occurs-incurring undesired downtime and expense.

The mechanism of rouging is still not fully understood and as a result there are some myths and misconceptions about what it is and how to prevent it. Essentially, rouge is a form of rust, i.e., iron oxide, but different than the heavy rust seen when stainless steel is not cleaned properly after heat treatment or welding. While normal rust is a result of improper cleaning during manufacture, rouge is a much thinner layer that occurs when perfectly cleaned stainless steel reacts with high-purity water environments. Rouge seems to be more prevalent at temperatures in excess or 60° C.

We know that stainless steels achieve their corrosion resistance by developing a very thin microscopic chromium oxide layer. The general consensus about rouging is that certain services, such as high purity water with very low oxygen content, dissolve this protective layer and allow the stainless steel to resume corroding. This corrosion is then responsible for the staining we call rouging. These stains have been analyzed as being various types of iron oxide as well as containing traces of chromium and nickel.

While mainly an aesthetics problem, most people still want to prevent rouge in their systems. One commonly held belief is that the ferrite phase in cast stainless steels or welds causes rouging, and purchasers of valves and other equipment frequently impose strict limits on the ferrite content of cast stainless steels. Since wrought stainless steels with no ferrite also experience rouging, it doesn't appear that ferrite is the culprit.

A study conducted by AvestaPolarit1, found that the water's gas content and a metal's surface finish were influential for rouging. Basically, water with high oxygen and low carbon dioxide content was less likely to cause rouging as were electro-polished surfaces of the metal components. This study also found no significant correlation for the different alloy grades, including duplex stainless steels with their high ferrite content.

Since most people find rouge objectionable in their systems, much attention has been given to its removal. Various acids and chelates are used to clean systems of rouge, but these can leave behind their own contaminates or films. In addition, if acid exposure is not controlled closely, the acid can etch the metal surfaces thus destroying the expensive electro-polished surfaces. Therefore, the most effective way to prevent rouge is by somehow introducing sufficient oxygen to the system, which helps maintain the protective chromium oxide layer.

  • Latest Post

  • Popular

  • Links

  • Events

Advertisement

Looking for a career in the Valve Industry?

ValveCareers Horiz

To learn more, watch the videos below or visit ValveCareers.com a special initiative of the Valve Manufacturers Association