01162017Mon
Last updateFri, 13 Jan 2017 3pm

i

Is Your Favorite a 2016 Top 10 Article?

Is Your Favorite a 2016 Top 10 Article?

Since VALVEMagazine.com was inaugurated ...

Portable Alloy Verification Devices

Portable Alloy Verification Devices

Q: What are the differences between the ...

Force and Direction Controls for Valve Actuators

Force and Direction Controls for Valve Actuators

Valve actuators deliver either linear or...

The Weekly Report

New Products

  • ja-news-2
  • ja-news-3

Industry Headlines

Industry Headlines

David Paradis Named President of Weir Flow Control Division

2 DAYS AGO

The Weir Group PLC has appointed David Paradis to its group executive as president of the Weir Flow Control Division. He will take up this new role on January 23, 2017. Paradis succeeds John Heasley who was appointed Weir Group CFO in October 2016.

Paradis is currently president of Weir Oil & Gas&r...

Readmore

GE, Transocean Announce Performance-Based Service Agreement

4 DAYS AGO

GE Oil & Gas has secured a new contractual service agreement (CSA), valued at approximately $180 million, with Transocean. Under the agreement , GE will provide condition-based monitoring and maintenance services for pressure control equipment on seven of Transocean’s rigs over the next 10 t...

Readmore

$4.17B Canadian Trans Mountain Pipeline Expansion Approved

3 DAYS AGO

Kinder Morgan’s Trans Mountain Expansion Project has received its environmental certificate from British Columbia, Canada. The proposed $4.17 billion Trans Mountain Expansion Project would increase the capacity of the pipeline to 890,000 barrels per day. The current capacity of the pipeline is 3...

Readmore

New Upstream Oil & Gas Industry Projects to Double in 2017

4 DAYS AGO

Wood Mackenzie forecasts the investment cycle will show the first signs of growth in 2017 since 2014 and final investment decisions (FIDs) will double , compared with 2016.

Malcolm Dickson, a principal analyst for Upstream Oil and Gas for Wood Mackenzie, said: "2017 will demonstrate how efficient the o...

Readmore

World Bank: U.S. Could Boost Global Economy in 2017

3 DAYS AGO

Global growth for 2017 is projected at 2.7%, 0.1% lower than the June 2016 forecast, and 0.4% higher than the estimate for 2016. Going forward, according to the World Bank, global growth is projected to pick up modestly, reaching 2.9% by 2018.

Downside risks to global growth include increasing policy u...

Readmore

Implementing Factory of the Future Will Reduce Conversion Costs 40%

4 DAYS AGO

Investments in the factory of the future will pay off, and industrial companies that begin implementation today will save up to 40% of their conversion costs in ten years. To succeed, however, manufacturers have to leverage the potential of modular production concepts and new technologies, as well a...

Readmore

Testing High-Nickel Alloy Castings in Refineries

vmspr12_nickel_1

Refiners today are increasingly dealing with more corrosive feedstocks that present new demands on valves in the process. However, maintenance personnel can detect problems before they become major issues by using different testing methods.

In 2009, a Minnesota-located refinery was experiencing through-wall leakage with several Class 300 rotary valves tasked with controlling crude unit vacuum prefractionator charge heaters. Maintenance personnel removed insulation from the valves and noted coke residue on the surface of the valve bodies, which identified for them where the leaks were occurring (Figure 1).

vmspr12_nickel_fig1Figure 1. Removing insulation from around the ball valve in question revealed leakage locations.Fortunately, this particular situation did not result in a safety event or a fire. Instead, it illustrates how the refining industry’s use of increasingly corrosive feedstocks can combine with unknown casting defects to cause potential valve problems.


THE INVESTIGATION/ EVALUATION

Five valve body castings, all grade CW2M (cast alloy C), were returned from the refinery to the manufacturer for evaluation using both nondestructive and destructive tests.

The nondestructive tests performed on the returned castings included visual examination, pressure testing and liquid penetrant (LP) examination.

Visual examination did not reveal any signs of corrosion on the wetted casting surfaces of the returned valves, which included both as-cast and machined surfaces.

The pressure testing used water at 1125 psig (7.76 megapascals or MPa) followed by helium at 150 psig (1.0 MPa). LP testing was performed to the requirements of ASTM A903 Level III, which considers linear and rounded indications exceeding 3/16 inch (4.8 millimeters) to be relevant. The helium and hydrostatic water tests revealed no leaks. Apparently, the hydrocarbon or potential coking sealed the leak paths once the valves were brought down to ambient temperature and removed from service.

LP testing of the castings revealed indications on the exterior surface—a lesser number of indications were on the interior, cored surfaces. These indications were on both as-cast and machined surfaces. Most of the LP indications were shallow [<0.02 inch (0.5 millimeters)] and removed with minor grinding. However, on the neck area of some castings, grinding did not remove the indications. The defect progressed through the wall of the casting and could represent a leak path. (Note that all of the returned valves had through-wall leaks in the neck area.)

Destructive testing, including metallographic examination, scanning electron microscopy (SEM) and energy dispersive spectrographic analyses, was performed on several of the returned castings.

vmspr12_nickel_fig2Figure 2. Opened defect showing three zones of fracture. Original magnification 11x. For example, corrosion testing was done on one valve body casting to compare results to maximum acceptance values previously set for this material grade. The test environment was boiling ferric sulfate-sulfuric acid per ASTM G28 Practice A. Although this standard is intended for wrought product forms, the practice A test method is also useful for castings. The corrosion rate was 140 milli-inches per year or mpy (3.5 millimeters/year or mm/y) compared to the manufacturer’s acceptance criteria of 360 mpy (9.1 mm/y) maximum. The grain boundaries were visible, which is typical for this grade. Of importance to this issue is the fact that this is a very severe test that does not represent actual applications for CW2M but does detect susceptibility of weld metal and heat-affected zone to intergranular corrosion attack.

vmspr12_nickel_fig3Figure 3. Rounded dendrite fingers indicating a shrinkage defect. Original magnification 600x.Fracture surfaces from the neck area of the same valve body were examined using SEM (Figure 2). The first zone examined was an outer layer that was approximately 0.03 to 0.06 inch (0.8 to 1.5 millimeters) thick. This chill layer solidifies rapidly when the molten metal first contacts the mold surface.

The second layer or zone 2 of the fracture has a dendritic pattern. This pattern represents columnar grains that grew perpendicular from the chill layer during the balance of the solidification process. The neck was cast solid so all the grain growth was from the outer diameter to the center. The center of the neck was then bored out during machining of the casting.

Zone 3 was ductile, dimple shear. This is the fracture mode seen on any mechanical break produced in the lab.

Within the dendritic zone of some of the fractures were rounded dendrite arms (Figure 3). The rounding indicates a shrinkage defect caused by an isolated area of liquid that was frozen off from the riser system because it was not properly fed. When the liquid was consumed during solidification, the dendrite arms could not continue to grow, leaving the blunted tips. Dark areas, which were identified as oxide films formed from exposure to air during casting solidification or heat treatment, were also found on the lab fractures. This proves the fractures were present before the casting went into service.

vmspr12_nickel_fig4Figure 4. Photomicrograph showing the leak path and the continuation of the grain boundary. Original magnification 500x.Inclusions and porosity also were visible. The inclusions were mold sand, slag and oxides. The grains were very large compared to wrought product forms—about 1/4 to over 1/2 inch (6 to 13 millimeters). The grain boundaries were the intersection of the dendrites formed during solidification. One leak path was cross-sectioned (the photomicrograph in Figure 4 shows the continuation along a grain boundary).

  • Latest Post

  • Popular

  • Links

  • Events

Advertisement

Looking for a career in the Valve Industry?

ValveCareers Horiz

To learn more, watch the videos below or visit ValveCareers.com a special initiative of the Valve Manufacturers Association