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Improving Valve Sealing Performance and Reliability

Improving Valve Sealing Performance and Reliability

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A Primer on Fugitive Emissions

A Primer on Fugitive Emissions

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The State of Industrial Distribution in 2017

The State of Industrial Distribution in 2017

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Industry Headlines

ITT Reports 2016 Fourth-Quarter, Full-Year Results

Thursday, 16 February 2017  |  Chris Guy

On a GAAP basis, ITT Corporation delivered revenue of $588 million in the fourth quarter of 2016, reflecting a 12% decline that included a 2% negative...

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Industry Headlines

ITT Reports 2016 Fourth-Quarter, Full-Year Results

4 DAYS AGO

On a GAAP basis, ITT Corporation delivered revenue of $588 million in the fourth quarter of 2016, reflecting a 12% decline that included a 2% negative impact from foreign exchange. GAAP segment operating income decreased 12% .

In the Industrial Process segment, total revenue decreased 29% to $212 milli...

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Delta Centrifugal Rejoins VMA

4 DAYS AGO

This week VMA welcomed back associate member Delta Centrifugal Corporation of Temple, TX after a one year absence from the association.

Delta produces custom-made castings. Delta’s operations include Texas Stainless, Inc. Texas Stainless is a metals distributor and sells castings produced by Delt...

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How New U.S. Policies Will Affect the Chemical Industry

5 DAYS AGO

“In 2017, barring a recession in the U.S. and Europe or a slowdown in China, Moody’s Investor Service expects EBITDA in the chemicals industry to slip by 1 or 2% year-over-year.”

A new report from PwC predicts that the Trump administration “is likely to embrace policies that are...

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$2.2 Billion Investment Approved for Mad Dog Phase 2 Project

6 DAYS AGO

BHP Billiton has approved expenditure of $2.2 billion for its share of the development of the Mad Dog Phase 2 project in the Gulf of Mexico. During the fourth quarter of 2016, BP, which holds a 60.5% participating interest, sanctioned the Mad Dog Phase 2 project.

Mad Dog Phase 2, located in the Green...

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Philly Fed Manufacturing Conditions Continued to Improve in February

4 DAYS AGO

The index for current manufacturing activity in eastern Pennsylvania, southern New Jersey and Delaware increased from a reading of 23.6 in January to 43.3 this month and has remained positive for seven consecutive months. The share of firms reporting growth continues to increase: More than 48% of the ...

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Industrial Production Down 0.3% in January

5 DAYS AGO

Industrial production decreased 0.3% in January following a 0.6% increase in December. In January, manufacturing output moved up 0.2%, and mining output jumped 2.8%. The index for utilities fell 5.7%, largely because unseasonably warm weather reduced the demand for heating. At 104.6% of its 2012 avera...

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Materials Selection for Deepwater Gate Valves

spr11_deepsea_fig1Figure 1. A typical subsea installation showing valves, manifolds and jumpers

With the discovery of oil and gas in water depths thousands of feet below the surface, selection of valves is more important, difficult and complicated. Gate valves, which are often used in subsea applications, are available today in a wide selection of materials, but choosing them requires knowledge of new challenges and established standards.

In years past, the materials used to handle corrosive service in the sea faced mainly the challenges of hydrogen sulfide (H2S), carbon dioxide (CO2) and chlorides. With deepwater well drilling, the newer subsea systems being drilled also need to handle chemicals that will minimize paraffin, asphaltene, hydrates and scale formation as well as provide corrosion inhibitions. These chemicals, however, have adverse effects on metallic and non-metallic materials, and the problem is compounded when materials have to handle produced fluids, annular fluids and the injected chemicals. Also, with subsea systems, the effects of hydrogen embrittlement from the cathodic protection system have to be taken into account. For this reason, choosing the materials to be used in gate valves for subsea is especially challenging.

WHAT GOES INTO THE CHOICE

In selection of materials for subsea gate valves, the following must be considered:

  • Composition of produced fluids in contact with valves and internal parts—all wetted parts
  • Service temperatures
  • Operating pressure ranges
  • Galvanic effects from contact of dissimilar materials
  • Crevice corrosion at seal and flange faces
  • Temperature and chemical resistance for non-metallic materials
  • Cathodic protection (CP) on materials
  • Effectiveness of coatings on materials
  • Weldability for weld overlay
  • Material availability and cost
  • Compatibility of materials with injected fluids

 


VALVE BODY MATERIALS

Several organizations provide recommendations for the selection of materials for valves. These include the National Association for Corrosion Engineers (NACE) and American Petroleum Institute (API).

NACE only covers metallic material requirements for resistance to sulfide stress cracking (SCC) for oilfield equipment, which is not intended to include design specification. (Other forms of corrosion and other modes of failure are outside the scope of NACE’s standard and should be considered in design and operation of equipment.) NACE also has requirements for low-alloy materials exposed to sour service. For example, the organization requires that hardness for alloy materials be limited to HRC 22 maximum. Nickel content is limited to 1% maximum, and NACE also has proposed heat treatment such as normalized, normalized and temper, and quench and temper.

API has several standards, such a specification 17D “Specification for Subsea Wellhead and Christmas Tree Equipment,” which uses the material requirements of API 6A.

Specification API 6A covers a number of specific areas for subsea valves, including strength, impact and quality testing. Strength level depends on the pressure rating of the equipment. For example, for flanged end connections, equipment used to pressure levels of 10,000 psi must be manufactured from material having a minimum yield strength of 60,000 psi. Equipment exceeding 10,000 psi pressure must be designed using equipment with specified yield strength of 75,000 psi (refer to API 6A Table 5.2).

Once the fluids that will be produced have been determined, valve selection can occur. Besides the challenges the fluids will produce, as well as the temperatures and pressures involved, the service conditions must also be considered. This includes how long the equipment might be exposed to seawater. Alloy steel will handle most benign conditions, including low CO2 for short periods of time, but even short seawater exposure can cause corrosion of critical components. This is especially true if seawater is trapped in those components and cannot be flushed out in a timely manner. Even with benign conditions, there is need for long-term life—in many cases over 25 years.

Valves as specified using API and NACE standards to handle strength and corrosive requirements can be grouped as follows with typical materials and applicable service conditions:


Stainless-steel Valves
spr11_deepsea_fig2Figure 2. Typical subsea tree assembly

When environments call for stainless steels such as 410 and F6NM, they may have similar corrosion resistance in oilfield environments; however, they have significant differences in weldability. Stainless 410 in the wrought and welded condition has lower impact toughness than F6NM. Welds of 410 have lower toughness, and depending on the operation, F6NM is often used if there is a risk of Joule Thomson effect (the temperature change of a gas or liquid forced through a valve or porous plug while kept insulated so that no heat is exchanged with the environment) at the wellhead. Even though stainless steels such as 410 and F6NM have good corrosion resistance and can handle mild corrosive conditions, weld overlay of critical sealing surfaces with corrosion-resistant alloy (CRA) is used to minimize pitting.


Duplex Stainless-steel Components

Although duplex stainless steels have good corrosion resistance in most environments, the use of these materials is limited for wellhead equipment because of the danger associated with sigma formation during heat treatment in large section thicknesses. Improper heat treatment not only results in poor corrosion resistance, but also poor toughness property. Duplex stainless steels require a satisfactory balance between ferrite and austenite both in the wrought and welded structures. Super duplex is specified where the Pitting Resistance Index (PRE) exceeds 40, whereas duplex is specified for thin components.

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