Thermodynamic Processes: Flashing and Cavitation
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- How can relatively clean and clear water damage a valve?
- Why does it take longer to hard boil an egg in Denver than in Los Angeles?
- Why does water squirt farther out of a garden hose when I place my thumb over the end?
- How can the gas in my liquid propane grill last so long?
- What is that noise I hear in a pump when I fail to charge the downstream line?
- Can I prevent flashing and cavitation? If not, can I minimize the damage they cause to valves?
These two figures show that, while cavitation damage looks very different compared to flashing, the result is the same: loss of throttling and shut-off capability. Both kinds of damage are the result of related, but very different, processes.
PROCESS PRESSURE AND VAPOR PRESSURE
The place to begin in understanding the differences is by exploring what the terms “flashing” and “cavitation” actually mean. But to get to that point, we should first discuss another term: “vapor pressure.” The vapor pressure (PV) of a fluid is the pressure at which a liquid will begin the thermodynamic process of changing to vapor.
Similarly, under a condition of constant pressure, a change in temperature can also result in a phase change. PV of a fluid increases as the fluid temperature increases. If the fluid temperature is increased to the point where PV exceeds the local pressure (which is often the atmospheric pressure), vaporization will occur. This process is boiling.
In other words, flashing occurs when we lower the pressure at a constant temperature, and boiling occurs when we raise the temperature at a constant pressure. (This ties back to our egg example: It can take a bit longer to boil an egg in Denver than Los Angeles because the average atmospheric pressure is slightly lower in the “Mile-high” city of Denver—water boils at a slightly lower temperature there than it does near sea level.)
When a liquid is flowing through a conduit, such as a pipe or a garden hose, and it encounters a restriction, such as a valve (or your thumb on the end of the hose), it accelerates to a higher velocity. Why does this happen? It occurs because, when a liquid encounters a smaller flow area, the liquid must accelerate to maintain continuity—that is, to retain a relatively constant volumetric flow rate. This is much the same as the way a river tends to meander and run slowly when it’s flowing through a wide plain, but becomes fast-moving rapids or whitewater when the river encounters a narrow canyon. Boyle’s law, Bernoulli’s principle and Euler’s formula show us that the pressure in a restricted flow area (such as a valve) will be lower than in a larger pipe section.
These ideas are shown graphically in Figure 4.
Figure 5 shows an example of flashing that occurs when using a liquid propane (LP) gas grill. At temperatures above -44°F (-42°C), the vapor pressure of propane is greater than atmospheric pressure. However, the tank that contains the LP is typically pressurized to greater than 10 psig so the propane remains as a liquid within the tank. As the liquid passes through the tank-mounted valve and pressure regulator, fluid pressure drops well below its vapor pressure, causing the LP to flash entirely to a vapor. For typical conditions, propane has almost 300 times greater volume as a gas at standard atmospheric pressure (known as 1 atmosphere) than as a liquid within a pressurized tank. That is why the relatively small volume LP tank can last so long on a gas grill.
The gas grill example would be called an “open system,” because it ultimately vents to the atmosphere and can exchange matter and energy with that much larger system (our atmosphere). When a liquid flows through a piping system, it often is considered a “closed system,” because it can exchange energy but not exchange matter with an external system such as the atmosphere. In closed systems, all process conditions need close consideration to determine whether flashing may occur.
When shock waves from local bubble implosion impact against valve component surfaces, typical materials of construction for industrial valves can be work-hardened and fatigued. As the surfaces become brittle and less resistant to local fracture, they also are subjected to liquid micro-jets that essentially deteriorate the material with time. This process creates the grainy appearance unique to cavitation damage.
PROTECTING VALVES FROM DAMAGE
Generally speaking, valve manufacturers use one or more design strategies to protect valves from the potentially detrimental effects of flashing and cavitation. These strategies can be described as “resistance,” “isolation” or “elimination.”
Resistance strategies use materials that are very hard, that have a high fracture toughness or fatigue strength or that are less vulnerable to erosion damage through other means. Isolation design strategies involve designing flow paths that minimize the impingement of flashing or cavitation onto critical valve surfaces. Elimination strategies include using tortuous paths or true engineered staging of pressure drops across the valve. They also include adding a valve or orifice plate to split the pressure drop across multiple devices; this creates a greater P2 at the first device, reducing the potential for cavitation. Aspirating atmospheric air or injecting higher-pressure air into a valve is a third example of an elimination strategy. Manufacturers may also combine these strategies for heightened protection against damage.
Materials of construction should be chosen to resist both mechanical attack and chemical attack. Mechanical attack occurs in two forms: erosion (including abrasive, flashing and/or cavitation) and material deformation and subsequent failure. After a period of mechanical attack, many of the protective coatings of a material (films, oxides, etc.) are physically removed, making the base material more vulnerable to chemical attack. Figure 9 shows two valve plugs exposed to similar flashing conditions for similar durations.
Isolation means directing the flow path in a way that prevents or minimizes impingement of the process fluid onto critical surfaces. Figure 10 shows cross-sectional views of angle body valve designs. Angle valves, when oriented so that the flow passes through the valve as shown in this figure (commonly called a flow-down orientation), allow flashing or cavitation to primarily occur after the fluid has passed through the trim. Ideally, most energy—and potential for damage—associated with flashing or cavitation will then dissipate in the flow stream rather than come in contact with the trim or other valve flow passages.
Figure 11 shows a computational fluid dynamics model of an eccentric plug rotary valve, specifically designed for erosive service, in a reverse flow orientation. The high-velocity region of the flow, where the vena contracta occurs downstream of the valve plug, actually occurs past the plug at the valve outlet. Again, isolation and resistance strategies can be combined by flowing in this reverse orientation and using wear-resistant materials for the seat and outlet liner.
Drilled hole cages, tortuous paths and other trim designs are used by valve manufacturers to carefully manage the internal vena contracta pressure so it is always above the fluid vapor pressure. This minimizes or prevents the bubble formation altogether, which eliminates the cavitation as well. Figure 12 shows a drilled hole cage (left) that combines all three design strategies: resistance (hard materials), isolation (flow down) and elimination (pressure staging). If carefully designed, the hole geometry, diameter and spacing also help to isolate the individual jets as the flow passes through the cage.
A more severe cavitating service may require additional design strategies, such as those shown on the right of Figure 12. This design uses all of the approaches previously discussed with the addition of axial pressure staging as the flow passes through the valve trim. This particular design is capable of handling up to 6,000 psid pressure drops while minimizing or eliminating cavitation and associated damage.
Flashing and cavitation are thermodynamic processes resulting from process fluid properties and process conditions. It is important to know both the fluid properties (such as vapor pressure) and the system properties (such as process pressure and temperature) to understand whether cavitation or flashing are potential issues to address in valve selection and application. Flashing and cavitation can cause significant valve damage, even with clean fluids that do not contain any solids. Many valve design approaches will handle flashing and cavitation, but they generally can be categorized as using resistance, isolation and elimination. Understanding these three general principles can help in selecting the ideal valve design for tough applications.
- Fisher Controls International LLC. (2011). Control Valve Source Book Pulp & Paper. In F. C. LLC, Control Valve Source Book Pulp & Paper (pp. 4-6, 4-7). U.S.A.: http://www.documentation.emersonprocess.com/groups/public/documents/book/d103540x012.pdf.
- Machado, G. (2009, 08 01). Polymeric Solution for Pump Cavitation. Retrieved 05 07, 2015, from Electric Power: http://www.powermag.com/polymeric-solution-for-pump-cavitation/
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